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IMBIBITION
- The absorption of water by the solid particles of an adsorbent causing it to enormously increase in volume without forming a solution is called imbibition .
- Solid substances or adsorbents which take part in imbibition are called imbibants , e.g. , seeds , dry wood .
- The liquid ( usually water ) which is imbibed is known as imbibate.
- The imbibate is held in between and over the surface of particles of the solid substance through the processes of capillarity and adsorption
- Plant imbibants are hydrophilic ( Gk . hydor , water , philein to love ) colloids .
- They have a highly negative water potential . As a result when they come in contact with water ( yw = 0 ), a steep water potential gradient is established .
- Water diffuses rapidly into the adsorbent .
- The process will continue till an equilibrium is established .
- Amount of imbibition depends upon ( i ) Water potential gradient between adsorbent and water and ( ii ) Affinity of adsorbant for water
- Imbibition increases the volume of the imbibant, but the increase is less than the volume of water absorbed .
- It is caused by holding of water in between and over the surface of imbibant particles .
- Water molecules are immobilised.
- Their kinetic energy is released in the form of heat ( heat of wetting ) .
- The swelling imbibant also develops a pressure called imbibition pressure ( matric potential ) .
- Air dried Pea seeds on coming in contact with water can develop an imbibition pressure of upto 1000 bars ( = 100 MPa ) .
- This is tested by placing dry seeds in a tin , adding water upto their upper level and then tightly putting the lid over it .
- Within an hour the lid will be blown off .
- Alternately fill a gas jar 34 with dry seeds .
- Pour water upto the brim . Cover the cylinder with lid and place a weight over the lid .
- Within a couple of hours the lid alongwith weight is lifted .
- Imbibition capacity is maximum in phycocolloids followed by proteins, starch and cellulose .
- Lignin is hydrophobic . It , therefore , does not show imbibition of water ) Imbibition is influenced by a number of factors like texture
- ( looseness more and compactness less imbibition ) of the imbibant , temperature ( rises with rise of temperature ) , pressure ( decreases if pressure is against imbibant ) , electrolytes ( decreases ) and pH (decreases or increases depending upon charge of imbibant ).
- Imbibition plays an important role in absorbing and retaining water.
- (i) Absorption of water by young cells is mostly through imbibition.
- (ii) Water is absorbed by the germinating seeds through imbibition.
- (iii) Breaking of the seed coat in germinating seeds is due to greater imbibitional swelling of the seed kernel (stareh and protein) as compared to seed coverings (cellulose).
- (iv) Seedling is able to come out of soil due to development of imbibition pressure.
- (v) Imbibition pressure developed during germination of seeds and spores can break asphalt roads and concrete pavements.
- (vi) Jamming of wooden frames during rains is caused by swelling of wood due to imbibition.
- (vii) In older times, it was used in breaking the rocks and boulders. Wooden pegs were inserted in rocks. They were then made wet. As a consequence the wooden pegs developed huge imbibition pressures that could break the rocks into pieces.
- (viii) Fruits of many plants come to develop matric potential in addition to their osmotic potential in order to maintain inflow of water even under conditions of water scarcity.
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